Covalent Functionalization of Strained Graphene
نویسندگان
چکیده
منابع مشابه
Covalent functionalization of strained graphene.
An enhancement of the chemical activity of graphene is evidenced by first-principles modelling of the chemisorption of hydrogen, fluorine, oxygen and hydroxyl groups on strained graphene. For the case of negative strain or compression, chemisorption of the single hydrogen, fluorine or hydroxyl group is energetically more favourable than those of their pairs on different sublattices. This behavi...
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Graphene functionalization with organics is expected to be an important step for the development of graphene-based materials with tailored electronic properties. However, its high chemical inertness makes difficult a controlled and selective covalent functionalization, and most of the works performed up to the date report electrostatic molecular adsorption or unruly functionalization. We show h...
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ژورنال
عنوان ژورنال: ChemPhysChem
سال: 2012
ISSN: 1439-4235
DOI: 10.1002/cphc.201100847